I Valence Electrons



  • You can find valence electrons with a shortcut using the periodic table, but it’s good to only do that after you understand why the shortcut works, and to do.
  • Comprehensive information for the element Iodine - I is provided by this page including scores of properties, element names in many languages, most known nuclides and technical terms are linked to their definitions.

The electrons of an atom are typically divided into two categories: valence and core electrons. Valence electrons occupy the outermost shell or highest energy level of an atom while core electrons are those occupying the innermost shell or lowest energy levels. This difference greatly influences the role of the two types of electrons in a chemical reaction. Generally, valence electrons can participate in the formation of chemical bonding, but core electrons cannot. While core electrons are not involved in bonding, they influence the chemical reactivity of an atom.

In chemistry, valence electrons are the electrons that are located in the outermost electron shell of an element. Knowing how to find the number of valence electrons in a particular atom is an important skill for chemists because this information determines the kinds of chemical bonds that it can form and, therefore, the element's reactivity.

The electron configuration of a oxygen atom is

[ce{O}: ,1s^22s^22p^4 label{1}]

which may be shorted

[ce{O}:, [He]2s^2 2p^4 label{2}]

Number

where the ([He]) stands for the configuration of helium ((1s^2)). Similarly, the configuration of calcium with 20 electrons can be written

[ce{Ca}:, [Ar]4s^2 label{3}]

where the ([Ar]) stands for the configuration of argon ((1s^22s^22p^6 3s^2 3p^6)). Electronic configurations that are the same as noble gases are very stable since they have a full octet (except helium with a full 1s orbital).

The (1s) electrons in oxygen do not participate in bonding (i.e., chemistry) and are called core electrons. The valence electrons (i.e., the (2s^22p^4) part) are valence electrons, which do participate in the making and breaking of bonds. Similarly, in calcium (Equation (ref{3})), the electrons in the argon-like closed shell are the core electrons and the the two electrons in the 4s orbital are valence electrons.

Example (PageIndex{1}): Cobalt

What are the core and valence electrons in cobalt?

Solution

Start by writing the electron configuration of cobalt with 27 electrons:

[1s^22s^22p^63s^23p^64s^23d^7 nonumber]

However, argon has the electronic structure (1s^22s^22p^23s^23p^6), so we can rewrite the configuration as

[[Ar]4s^23d^7 nonumber]

The two electrons in the (4s) orbital and the seven electrons in the (3d) are the valence electrons: all others are core electrons.

The periodicity of valance electrons can be seen in the Periodic Table. Basically, the periodicity is only applied to the main group elements, while in transition metals, rules are complex.

The core electrons remain the same in the increase of group numbers in the main group elements. On the other hand, the valance electrons increase by one from left to right of a main period, and remain the same down the column of a main group. This evolution gives periodical change in property of a period, and similar chemical property of a group, which is called periodical trend. The number of valence electrons in a main period is the same as its group number. The table below shows this rule clearly.

Under construction

Figure 1: 1A + 2A are metals. 3A to 8A are non-metals.

However, this periodicity cannot be applied to the transition group, which is more complicated than that of the main group. Although the outermost electrons can be easily determined, the apparent valence electrons considered in chemical reactivity are complex and fluctuated. Electrons going into d sublevel can play either a role of valence electrons or shielding electrons. So there is not always a certain number of apparent valence electrons. The number of apparent valence electrons for the first transition metal period is shown in the table below.

Under construction

Figure 2: Valence electrons for transition metals.

Relationship with Chemical Reactivity

Electrons

The chemical reactivity of an atom is mainly determined by valence electrons. Atoms which have a complete shell of valence electrons tend to be chemically inert. Atoms with one or two valence electrons are highly reactive. This phenomenon can be explained by Hund's rule, which states that orbitals that are empty, half-full, or full are more stable than those that are not. For example, Ne is chemically inert because it has two valence electrons that fill its outermost shell which makes it stable compared to atoms such as Al, which has three valence electrons, but its valence electrons does not fill its outermost shell.

Although core electrons do not take part in chemical bonding, they play a role in determining the chemical reactivity of an atom. This influence is generally due to the effect it has on valence electrons. The effect can be observed from the gradual change of chemical reactivity in a group. As you go down a group, more shells are occupied by electrons, which increases the size of the atom. The more core electron shells an atom has, the larger the size of the atom, and the farther the valence electrons are from the nucleus, thus the valence electrons will experience less effective nuclear charge and will be easily lost. For example, (ce{Na}) and (ce{K}) can both react with water, but K has a more radical reaction because it has more shells of core electrons which makes the valence electron in its outermost orbital much easier to lose than the valence electron of Na.

References

  1. Miessler, Gary L., and Donald A. Tarr. Inorganic Chemistry. Upper Saddle River, NJ: Pearson Prentice Hall, 2010. Print.
  2. Brown, Ian David. The Chemical Bond in Inorganic Chemistry the Bond Valence Model. Oxford: Oxford UP, 2006. Print.

What is the number of core and valence electrons for I?

2 Answers

Explanation:

Iodine, #'I'#, is located in period 5, group 17 of the periodic table, and has an atomic number equal to #53#.

That means that a neutral iodine atom will have a total of #53# electrons surrounding its nucleus.

Now, out of these #53# electrons, some are considered core electrons and some areconsidered valence electrons.

#n_'total' = n_'core' + n_'valence'#

But how would you distinguish between the two types of electrons?

To do that, you need to look at the electron configuration of iodine, which looks like this

#'I: ' 1s^2 2s^2 2p^6 3s^2 3p^6 3d^10 4s^2 4p^6 5s^2 4d^10 5p^5#

You know that the valence electrons are defined as being the electrons located on the highest energy level of that atom, which is given by the principal quantum number, #n#, for main group elements.

Notice that, in iodine's case, the highest energy level is #n=5#. You have two subshells occupied with electrons on this energy level, #5s^2# and #5p^5#.

This means that iodine has a total of

#underbrace(2e^(-))_(color(blue)('from 5s subshell')) + overbrace(5e^(-))^(color(red)('from 5p subshell')) = '7 valence ' e^(-)#

The rest of the electrons will thus be core electrons.

#n_'core' = n_'total' - n_'valence'#

#n_'core' = 53 - 7 = color(green)('46 core 'e^(-))#

Therefore, a neutral iodine atom has #46# core electrons and #7#valence electrons.

Iodine has #7#valence electrons and #46# core electrons for a total of #53#, the atomic number.

Explanation:

Valence

Iodine is in the group 17 elements, known as halogens, and all of them have #7#valence electrons.

A valence electron is capable of bonding with valence electrons of another atom to complete the octet of electrons each atom needs in its outer shell.

The core electrons are not available for bonding with other elements

How To Get Valence Electrons

When more than one atom bonds with others, a molecule is formed. The completed molecule will not have an electron charge associated with it.

I Core And Valence Electrons

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